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Nacaphite

A valid IMA mineral species
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About NacaphiteHide

Formula:
Na2Ca(PO4)F
Colour:
Colourless
Lustre:
Vitreous
Hardness:
3
Crystal System:
Monoclinic
Name:
Named for its composition, including sodium (NAtrium), CAlcium, and PHosphorus.
It may be in a homologous series with seidozerite, as suggested by some authors.


Unique IdentifiersHide

Mindat ID:
2824
Long-form identifier:
mindat:1:1:2824:6

Similar NamesHide

NabaphiteA valid IMA mineral speciesNaBaPO4 · 9H2O

IMA Classification of NacaphiteHide

Classification of NacaphiteHide

8.BO.05

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
O : With only large cations, (OH, etc.):RO4 about 1:1
41.3.6.1

41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
3 : (AB)3(XO4)Zq
22.1.5

22 : Phosphates, Arsenates or Vanadates with other Anions
1 : Phosphates, arsenates or vanadates with fluoride

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
NcpIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of NacaphiteHide

Vitreous
Colour:
Colourless
Streak:
White
Hardness:

Optical Data of NacaphiteHide

Type:
Biaxial (-)
RI values:
nα = 1.508 nβ = 1.515 nγ = 1.52
2V:
Measured: 80° , Calculated: 80°
Max. Birefringence:
δ = 0.012
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars.

Surface Relief:
Moderate
Dispersion:
none

Chemistry of NacaphiteHide

Mindat Formula:
Na2Ca(PO4)F
Element Weights:
Element% weight
O31.994 %
Na22.987 %
Ca20.036 %
P15.485 %
F9.498 %

Calculated from ideal end-member formula.

Crystallography of NacaphiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P121/c1
Cell Parameters:
a = 13.3185(14) Å, b = 7.0964(8) Å, c = 10.6490(11) Å
β = 113.526(1)°
Ratio:
a:b:c = 1.877 : 1 : 1.501
Unit Cell V:
922.81 ų
Z:
8
Comment:
pseudo-orthorhombic C-centred (a = 10.65, b = 24.43, c = 7.10)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005738NacaphiteSokolova E V, Hawthorne F C (2001) The crystal chemistry of the [M3_11-14] trimeric structures: From hyperagpaitic complexes to saline lakes The Canadian Mineralogist 39 1275-1294BERJAYA20010293
0005594NacaphiteSokolova E V, Kabalov Y K, Ferraris G, Schneider J, Khomyakov A P (1999) Modular approach in solving the crystal structure of a synthetic dimorph of nacaphite, Na2Ca[PO4]F, from powder-diffraction data The Canadian Mineralogist 37 83-90BERJAYA19990293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.649 Å(100)
3.054 Å(45)
3.049 Å(40)
2.005 Å(40)
1.762 Å(33)
3.51 Å(24)
1.470 Å(21)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of NacaphiteHide

Place of Conservation of Type Material:
Geology Museum, Kola Branch, Academy of Sciences, Apatity, Russia, 5534.
Mining Institute, St. Petersburg, Russia, 1116/2.
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 79854.
The Natural History Museum, London, England, 1994,15.
Geological Setting of Type Material:
Ijolite-urtite pegmatite in an apatite deposit.

Synonyms of NacaphiteHide

Other Language Names for NacaphiteHide

Dutch:Nacaphiet
German:Nacaphit
Spanish:Nacaphita

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Nacaphite associated with NefedoviteNa5Ca4(PO4)4F
1 photo of Nacaphite associated with ThermonatriteNa2CO3 · H2O

Related Minerals - Strunz-mindat GroupingHide

8.BO.AriegilatiteBaCa12(SiO4)4(PO4)2F2OTrig. 3m(32/m) : R3m
8.BO.AravaiteBa2Ca18(SiO4)6(PO4)3(CO3)F3OTrig. 3m(32/m) : R3m
8.BO.TheuerdankiteAg3AsO4Iso. 43m : P43n
8.BO.10PetitjeaniteBi3(PO4)2O(OH)Tric. 1 : P1
8.BO.10SchumacheriteBi3(VO4)2O(OH)Tric. 1 : P1
8.BO.10PreisingeriteBi3(AsO4)2O(OH)Tric. 1 : P1
8.BO.15HechtsbergiteBi2(VO4)O(OH)Mon. 2/m : P21/b
8.BO.15SmrkoveciteBi2(PO4)O(OH)Mon. 2/m : P21/b
8.BO.15AtelestiteBi2(AsO4)O(OH)Mon. 2/m : P21/b
8.BO.20SahlinitePb14(AsO4)2O9Cl4Mon. 2/m : B2/b
8.BO.20KombatitePb14(VO4)2O9Cl4Mon. 2/m : B2/b
8.BO.25HeneuiteCaMg5(CO3)(PO4)3(OH)Tric. 1 : P1
8.BO.30NefedoviteNa5Ca4(PO4)4FTric.
8.BO.35Kuznetsovite[Hg2]2+Hg2+[AsO4]ClIso. 23 : P213
8.BO.40Artsmithite[Hg2]2+2Al(PO4)1.74(OH)1.78Mon. 2/m : B2/b
8.BO.45SchlegeliteBi7(AsO4)3(MoO4)2O4Orth. mmm(2/m2/m2/m)
8.BO.50Hereroite[Pb32(O,◻)21](AsO4)2[(Si,As,V,Mo)O4]2Cl10Mon. 2/m : B2/b
8.BO.50Erikjonssonite(Pb32O21)[(V,Si,Mo,As)O4]4Cl9Mon. 2/m : B2/b
8.BO.55Rudabányaite(Ag2Hg2)(AsO4)ClIso. 43m : F43c
8.BO.60SegerstromiteCa3(As5+O4)2[As3+(OH)3]2Iso. 23 : I213
8.BO.65WiklunditePb2(Mn2+,Zn)3(Fe3+,Mn2+)2(Mn2+,Mg)19(As3+O3)2[(Si,As5+)O4]6(OH)18Cl6Trig. 3m(32/m) : R3c

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for NacaphiteHide

References for NacaphiteHide

Reference List:

Localities for NacaphiteHide

Showing 9 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the BERJAYA symbol to view information about a locality. The BERJAYA symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

BERJAYA - This locality has map coordinates listed. BERJAYA - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. BERJAYA - Good crystals or important locality for species. BERJAYA - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Murmansk Oblast
    • Carbonatite Stock in the vicinity of Tul'ilukht Bay
Pekov (1998)
    • Koashva Mt
Arzamastsev et al. (2008)
33 IGC excursion No 47 +2 other references
    • Kukisvumchorr Mt
...
    • Lovozersky District
Pakhomovsky et al. (2014)
Pekov (1998) +1 other reference
      • Rasvumchorr Mine
Pavel M. Kartashov (n.d.)
Pekov I.V. et al. (2010)
 
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