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. 2009;48(9):1685-7.
doi: 10.1002/anie.200804712.

Water splitting by light with osmocene as photocatalyst

Horst Kunkely  1 , Arnd Vogler
Affiliations

Water splitting by light with osmocene as photocatalyst

Horst Kunkely et al. Angew Chem Int Ed Engl. 2009.

Abstract

Last but not least: A simple molecular redox system is used to split water into hydrogen and oxygen photochemically. Two separate photolyses are combined to a cyclic process (see scheme). Osmocene ([Cp(2)Os(II)] with Cp(-) = C(5)H(5)(-)) serves as photocatalyst.

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